Alexey Silakov
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14N HYSCORE investigation of the H-cluster of [FeFe] hydrogenase: evidence for a nitrogen in the dithiol bridge
A Silakov, B Wenk, E Reijerse, W Lubitz
Physical Chemistry Chemical Physics 11 (31), 6592-6599, 2009
Iron(IV)hydroxide pKa and the Role of Thiolate Ligation in C–H Bond Activation by Cytochrome P450
TH Yosca, J Rittle, CM Krest, EL Onderko, A Silakov, JC Calixto, ...
Science 342 (6160), 825-829, 2013
Identification and Characterization of the “Super‐Reduced” State of the H‐Cluster in [FeFe] Hydrogenase: A New Building Block for the Catalytic Cycle?
A Adamska, A Silakov, C Lambertz, O Rüdiger, T Happe, E Reijerse, ...
Angewandte Chemie International Edition 51 (46), 11458-11462, 2012
The Electronic Structure of the H-Cluster in the [FeFe]-Hydrogenase from Desulfovibrio desulfuricans: A Q-band 57Fe-ENDOR and HYSCORE Study
A Silakov, EJ Reijerse, SPJ Albracht, EC Hatchikian, W Lubitz
Journal of the American Chemical Society 129 (37), 11447-11458, 2007
Spectroelectrochemical Characterization of the Active Site of the [FeFe] Hydrogenase HydA1 from Chlamydomonas reinhardtii
A Silakov, C Kamp, E Reijerse, T Happe, W Lubitz
Biochemistry 48 (33), 7780-7786, 2009
Importance of the protein framework for catalytic activity of [FeFe]-hydrogenases
P Knörzer, A Silakov, CE Foster, FA Armstrong, W Lubitz, T Happe
Journal of Biological Chemistry 287 (2), 1489-1499, 2012
A model of the [FeFe] hydrogenase active site with a biologically relevant azadithiolate bridge: a spectroscopic and theoretical investigation
ÖF Erdem, L Schwartz, M Stein, A Silakov, S Kaur‐Ghumaan, P Huang, ...
Angewandte Chemie International Edition 50 (6), 1439-1443, 2011
Isolation and first EPR characterization of the [FeFe]-hydrogenases from green algae
C Kamp, A Silakov, M Winkler, EJ Reijerse, W Lubitz, T Happe
Biochimica et Biophysica Acta (BBA)-Bioenergetics 1777 (5), 410-416, 2008
The [FeFe]-hydrogenase maturase HydF from Clostridium acetobutylicum contains a CO and CN− ligated iron cofactor
I Czech, A Silakov, W Lubitz, T Happe
FEBS letters 584 (3), 638-642, 2010
Effect of flavoring chemicals on free radical formation in electronic cigarette aerosols
ZT Bitzer, R Goel, SM Reilly, RJ Elias, A Silakov, J Foulds, J Muscat, ...
Free Radical Biology and Medicine 120, 72-79, 2018
Optimized over-expression of [FeFe] hydrogenases with high specific activity in Clostridium acetobutylicum
G Von Abendroth, S Stripp, A Silakov, C Croux, P Soucaille, L Girbal, ...
international journal of hydrogen energy 33 (21), 6076-6081, 2008
Visualizing the reaction cycle in an iron (II)-and 2-(oxo)-glutarate-dependent hydroxylase
AJ Mitchell, NP Dunham, RJ Martinie, JA Bergman, CJ Pollock, K Hu, ...
Journal of the American Chemical Society 139 (39), 13830-13836, 2017
Significantly shorter Fe–S bond in cytochrome P450-I is consistent with greater reactivity relative to chloroperoxidase
CM Krest, A Silakov, J Rittle, TH Yosca, EL Onderko, JC Calixto, ...
Nature chemistry 7 (9), 696-702, 2015
Spectroscopic and Electrochemical Characterization of the Iron–Sulfur and Cobalamin Cofactors of TsrM, an Unusual Radical S-Adenosylmethionine Methylase
AJ Blaszczyk, A Silakov, B Zhang, SJ Maiocco, ND Lanz, WL Kelly, ...
Journal of the American Chemical Society 138 (10), 3416-3426, 2016
Experimental correlation of substrate position with reaction outcome in the aliphatic halogenase, SyrB2
RJ Martinie, J Livada, W Chang, MT Green, C Krebs, JM Bollinger Jr, ...
Journal of the American Chemical Society 137 (21), 6912-6919, 2015
Two distinct mechanisms for C–C desaturation by Iron (II)-and 2-(oxo) glutarate-dependent oxygenases: Importance of α-heteroatom assistance
NP Dunham, W Chang, AJ Mitchell, RJ Martinie, B Zhang, JA Bergman, ...
Journal of the American Chemical Society 140 (23), 7116-7126, 2018
Unusual Synthetic Pathway for an {Fe(NO)2}9 Dinitrosyl Iron Complex (DNIC) and Insight into DNIC Electronic Structure via Nuclear Resonance Vibrational …
AL Speelman, B Zhang, A Silakov, KM Skodje, EE Alp, J Zhao, MY Hu, ...
Inorganic chemistry 55 (11), 5485-5501, 2016
Function of the Diiron Cluster of Escherichia coli Class Ia Ribonucleotide Reductase in Proton-Coupled Electron Transfer
B Wörsdörfer, DA Conner, K Yokoyama, J Livada, M Seyedsayamdost, ...
Journal of the American Chemical Society 135 (23), 8585-8593, 2013
Characterization of a selenocysteine-ligated P450 compound I reveals direct link between electron donation and reactivity
EL Onderko, A Silakov, TH Yosca, MT Green
Nature Chemistry 9 (7), 623-628, 2017
A substrate radical intermediate in catalysis by the antibiotic resistance protein Cfr
TL Grove, J Livada, EL Schwalm, MT Green, SJ Booker, A Silakov
Nature chemical biology 9 (7), 422-427, 2013
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